A Transannular Beckmann Rearrangement in Liquid Sulfur Dioxide
نویسندگان
چکیده
منابع مشابه
Cyclopropenium ion catalysed Beckmann rearrangement.
1-Chloro-2,3-diphenylcyclopropenium ion was found to be a very efficient organocatalyst (3 mol% loading) for liquid phase Beckmann rearrangement of various ketoximes to the corresponding amides/lactams within 2 h in acetonitrile at reflux temperature. This is the first example of the application of the cyclopropenium ion as a catalyst, which opens up a new aspect of the synthetic utility of aro...
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A tricyclic lactam is reported in a four step synthesis sequence via Beckmann rearrangement and ring-rearrangement metathesis as key steps. Here, we used a simple starting material such as dicyclopentadiene.
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The ubiquity of sulfur dioxide as an air pollutant combined with reports of effects of the gas and its blood metabolite on DNA and chromosomes, prompted a study of possible mutagen action on mammalian oocytes. Utilizing in vitro and in vivo systems, mouse, ewe, and cow oocytes were examined for cytologic evidence of structural or numerical damage in meiosis. Fragmentation with rearrangement see...
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ژورنال
عنوان ژورنال: Bulletin of the Chemical Society of Japan
سال: 1959
ISSN: 0009-2673,1348-0634
DOI: 10.1246/bcsj.32.654